Novel 3D Network: From the Reaction of Polyamine with Pyromellitic Dianhydride

Under mild condition, the reaction of pyromellitic dianhydride with polyamine in methanol solution results in ammonium carboxylate salts rather than amide polymer. X-ray analysis indicates a manifestation of 3D network linked by N-H + > O m > H-N + hydrogen bonding for the three ammonium salts, in which the porous spaces are filled with water molecules.     

掺杂质子化石墨相氮化碳增强碳基太阳能电池中钙钛矿的结晶

钙钛矿层的品质极大影响钙钛矿太阳能电池性能. 然而,在溶液法生成多晶钙钛矿膜过程中会不可避免地形成缺陷和陷阱位. 通过在钙钛矿层中嵌入添加物改善钙钛矿晶化,用于减少和钝化缺陷是非常重要的. 本文合成一种环境友好的二维纳米材料质子化石墨相氮化碳(p-g-C₃N₄),并掺杂于碳基钙太阳能电池的钙钛矿层中. 实验证明,在钙钛矿前驱体溶液中添加p-g-C₃N₄不仅能调解碘铅甲胺(MAPbI₃)结晶的成核和生长速率,获得大晶粒尺寸的平滑表面,还能减少钙钛矿层的本征缺陷. 质子化过程在氮化碳表面引入活性基团-NH₂/-NH₃,它们和钙钛矿晶体表面N-H键发生强化学作用,有效地钝化电子陷阱,提高钙钛矿结晶质量. 结果表明,与不掺杂的对照电池(效率为4.48%)和掺杂石墨相氮化碳(g-C₃N₄)电池(效率为5.93%)相比,掺杂质子化石墨相氮化碳(p-g-C₃N₄)的电池获得了6.61%的较高效率. 本工作展示了一种通过掺杂改性添加物改善钙钛矿膜的简单方法,为碳基钙钛矿太阳能电池的低成本制备提供了建议.     

X射线自由电子激光试验装置

X射线自由电子激光试验装置(以下简称"SXFEL试验装置")是中国第一台X射线相干光源,其输出波长小于9 nm。这台基于0.84 GeV直线加速器、以掌握装置相关技术和实验演示种子型自由电子激光(FEL)级联与短波长回声型FEL为主要目标的自由电子激光装置,于2020年11月通过国家验收。本文将介绍SXFEL试验装置的基本情况和主要进展。     

Improvement of the large aperture Ti：sapphire amplifiers in the petawatt femtosecond laser system at SIOM

We report the recent improvement on the petawatt (PW) femtosecond Ti:sapphire chirped pulse amplification (CPA) laser system at Shanghai Institute of Optics and Fine Mechanics (SIOM), Chinese Academy of Sciences. By enlarging the sizes of the pump and signal beams in the large aperture Ti:sapphire amplifiers and optimizing the whole laser system, the output laser energy before the pulse compressor is upgraded to 42.6 J. Accordingly, the peak power of the laser system exceeds 1 PW. The shot-to-shot instability of the output laser energy at about 40 J is less than ±5%.     

A non-radial DEA approach to measuring environmental performance

Data envelopment analysis (DEA) has gained great popularity in environmental performance measurement because it can provide a synthetic standardized environmental performance index when pollutants are suitably incorporated into the traditional DEA framework. Past studies about the application of DEA to environmental performance measurement often follow the concept of radial efficiency measures. In this paper, we present a non-radial DEA approach to measuring environmental performance, which consists of a non-radial DEA-based model for multilateral environmental performance comparisons and a non-radial Malmquist environmental performance index for modeling the change of environmental performance over time. A case study of OECD countries using the proposed non-radial DEA approach is also presented. It is found that the environmental performance of OECD countries as a whole has been improved from 1995 to 1997.     

LOOMIS-WHITNEY'S INEQUALITY ABOUT MIXED BODY

In this article,the authors establish two theorems for mixed body,which are the generalizations of the well-known Loomis-Whitney's inequality.     

Effect of lithium chloride on allylation of zirconacyclopentadienes

The effects of lithium chloride on the allylation of zirconacyclopentadienes with allylic halides in the presence of CuCl have been studied. It is found that mono-allylation products are formed predominantly in the absence of lithium chloride, while the presence of lithium chloride leads to the formation of di-allylation products.     

MID-FACETS OF A SIMPLEX

The mid-facet of a simplex in n-dimensional Euclidean space which was introduced quite recently is an important geometric element. An analytic expression for the mid-facet area of a simplex is firstly given. In order to obtain the expression, the exterior differential method was presented. Furthermore, the properties of the mid-facets of a simplex analogous to median lines of a triangle ( such us for all mid-facets of a simplex,there exists another simplex such that its edge-lengths equal to these mid-facets area respectively, and all of the mid-facets of a simplex have a common point) were proved.Finally, by applying the analytic expression, a number of inequalities which combine edge-lengths, circumradius , median line, bisection area and facet area with the mid-facet area for a simplex were established.